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| Acceso al texto completo restringido a Biblioteca INIA Las Brujas. Por información adicional contacte bibliolb@inia.org.uy. |
Registro completo
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Biblioteca (s) : |
INIA Las Brujas. |
Fecha : |
12/11/2015 |
Actualizado : |
09/10/2019 |
Tipo de producción científica : |
Artículos en Revistas Indexadas Internacionales |
Autor : |
BESIL, N.; PÉREZ-PARADA, A.; CESIO, V.; VARELA, P.; RIVAS, F.; HEINZEN, H. |
Afiliación : |
NATALIA BESIL, Universidad de la República (UdelaR)/ Centro Universitario Regional Noroeste, Salto (CENUR); Universidad de la República (UdelaR)/ Facultad de Química; ANDRÉS PÉREZ-PARADA, Universidad de la República (UdelaR)/ Facultad de Química; VERÓNICA CESIO, Universidad de la República (UdelaR)/ Facultad de Química; PABLO NICOLAS VARELA PESSOLANO, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; CARLOS FERNANDO RIVAS GRELA, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; HORACIO HEINZEN, Universidad de la República (UdelaR)/ Centro Universitario Regional Noroeste, Salto (CENUR); Universidad de la República (UdelaR)/ Facultad de Química. |
Título : |
Degradation of imazalil, orthophenylphenol and pyrimethanil in Clementine mandarins under conventional postharvest industrial conditions at 4 °C. |
Fecha de publicación : |
2015 |
Fuente / Imprenta : |
Food Chemistry, 2016, v.194, p. 1132-1137. |
ISSN : |
0308-8146 |
DOI : |
10.1016/j.foodchem.2015.08.111 |
Idioma : |
Inglés |
Notas : |
Article history: Received 16 April 2015 / Received in revised form 25 August 2015 / Accepted 25 August 2015 / Available online 29 August 2015.
Chemical compounds studied in this article: Imazalil (PubChem CID: 37175) / Orthophenylphenol (PubChem CID: 7017) / Pyrimethanil (PubChem CID: 91650). |
Contenido : |
ABSTRACT.
The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues
found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially.
Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazalil residues were significantly different.
Final residue levels after 28 days of storage were 0.12?0.24 mg kg1 for imazalil, 0.68 mg kg1 for 2-phenylphenol and 0.56 mg kg1 for pyrimethanil for all the evaluated treatments.
2015 Elsevier Ltd. All rights reserved. MenosABSTRACT.
The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues
found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially.
Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazali... Presentar Todo |
Palabras claves : |
Degradation; Postharvest fungicides. |
Thesagro : |
CITRUS; FUNGICIDAS; TECNICA POSTCOSECHA. |
Asunto categoría : |
H20 Enfermedades de las plantas |
Marc : |
LEADER 02850naa a2200277 a 4500 001 1053857 005 2019-10-09 008 2015 bl uuuu u00u1 u #d 022 $a0308-8146 024 7 $a10.1016/j.foodchem.2015.08.111$2DOI 100 1 $aBESIL, N. 245 $aDegradation of imazalil, orthophenylphenol and pyrimethanil in Clementine mandarins under conventional postharvest industrial conditions at 4 °C. 260 $c2015 500 $aArticle history: Received 16 April 2015 / Received in revised form 25 August 2015 / Accepted 25 August 2015 / Available online 29 August 2015. Chemical compounds studied in this article: Imazalil (PubChem CID: 37175) / Orthophenylphenol (PubChem CID: 7017) / Pyrimethanil (PubChem CID: 91650). 520 $aABSTRACT. The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially. Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazalil residues were significantly different. Final residue levels after 28 days of storage were 0.12?0.24 mg kg1 for imazalil, 0.68 mg kg1 for 2-phenylphenol and 0.56 mg kg1 for pyrimethanil for all the evaluated treatments. 2015 Elsevier Ltd. All rights reserved. 650 $aCITRUS 650 $aFUNGICIDAS 650 $aTECNICA POSTCOSECHA 653 $aDegradation 653 $aPostharvest fungicides 700 1 $aPÉREZ-PARADA, A. 700 1 $aCESIO, V. 700 1 $aVARELA, P. 700 1 $aRIVAS, F. 700 1 $aHEINZEN, H. 773 $tFood Chemistry, 2016$gv.194, p. 1132-1137.
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4. | | FERRARI, V.; GIL, G.; HEINZEN, H.; ZOPPOLO, R.; IBÁÑEZ, F. Influence of Cultivar on Nutritional Composition and Nutraceutical Potential of Pecan Growing in Uruguay. Frontiers in Nutrition, 2022, volume 9, e868054. OPEN ACESS. doi: https://doi.org/10.3389/fnut.2022.868054 Article history: Received 02 February 2022; Accepted 30 May 2022; Published: 22 June 2022. -- Correspondence: Facundo Ibáñez, fibanez@inia.org.uy -- Edited by: Elena Ibañez, Institute of Food Science Research (CSIC), Spain. Reviewed by:...Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
Biblioteca(s): INIA Las Brujas. |
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7. | | BESIL, N.; CESIO, V.; BOLOGNA, F.; LUQUE, E.; PINTOS, P.; RIVAS, C.; HEINZEN, H. Disipación de fungicidas e insecticidas utilizados en campo en el cultivo de mandarinas, naranjas y limones. In: INIA (Instituto Nacional de Investigación Agropecuaria); Programa Nacional Producción Citrícola. Resultados de investigación en Citricultura: Genética, Sanidad, Productividad. Salto (Uruguay): INIA, 2015. p. 45-49 (Serie Actividades de Difusión; 752).Biblioteca(s): INIA Las Brujas. |
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9. | | BESIL, N.; PÉREZ-PARADA, A.; BOLOGNA, F.; CESIO, M.V.; RIVAS, F.; HEINZEN, H. Dissipation of selected insecticides and fungicides applied during pre-harvest on mandarin and orange trees in Uruguay. Scientia Horticulturae, 5 April 2019, Volume 248, Pages 34-40. Article history: Received 4 October 2018 / Revised 28 December 2018 / Accepted 29 December 2018 / Available online 9 January 2019.
Funding sources: Financial support from Instituto Nacional de Investigación Agropecuaria Uruguay,...Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
Biblioteca(s): INIA Las Brujas. |
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10. | | BESIL, N.; PÉREZ-PARADA, A.; CESIO, V.; VARELA, P.; RIVAS, F.; HEINZEN, H. Degradation of imazalil, orthophenylphenol and pyrimethanil in Clementine mandarins under conventional postharvest industrial conditions at 4 °C. Food Chemistry, 2016, v.194, p. 1132-1137. Article history: Received 16 April 2015 / Received in revised form 25 August 2015 / Accepted 25 August 2015 / Available online 29 August 2015.
Chemical compounds studied in this article: Imazalil (PubChem CID: 37175) / Orthophenylphenol...Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
Biblioteca(s): INIA Las Brujas. |
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12. | | PREVE, F.; ABELLA, I.; PEREIRA, D.; HEINZEN, H.; GONZÁLEZ, G.; PÉREZ, A. Lanas naturales y con bajo contenido de pesticidas. Agrociencia, 2009, v. 13, no. 3, p. 86Biblioteca(s): INIA Tacuarembó. |
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13. | | GÁMBARO, A.; ROASCIO, A.; HODOS, N.; MIGUES, I.; LADO, J.; HEINZEN, H.; RIVAS, F. The impact of sensory attributes of mandarins on consumer perception and preferences. Journal of Agriculture and Food Research, December 2021, volume 6, article 100196. OPEN ACCESS. doi: https://doi.org/10.1016/j.jafr.2021.100196 Article history: Received 20 November 2020, Revised 28 June 2021, Accepted 14 August 2021, Available online 19 August 2021, Version of Record 2 September 2021.
Corresponding author: Gámbaro, A.; General Flores, Uruguay;...Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
Biblioteca(s): INIA Las Brujas. |
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14. | | MIGUES, I.; CESIO, V.; GÁMBARO, A.; MOYNA, G.; RODRÍGUEZ, C.; LADO, J.; RIVAS, F.; HEINZEN, H. NMR metabolomics as a prediction tool for consumers acceptance of mandarins. (SI-O-7) [oral presentation]. Session I: Breeding, Genomics and Genetics. In: RIivas, F. (Ed.). IV International Symposium on Citrus Biotechnology. Book of Abstracts. Montevideo (UY): INIA. p. 17. (INIA Serie Técnica; 244).Tipo: Presentaciones Orales |
Biblioteca(s): INIA Las Brujas. |
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15. | | NIELL, S.; JESÚS, F.; PÉREZ, C.; MENDOZA, Y.; DIAZ, R.; FRANCO, J.; CESIO, V.; HEINZEN, H. QuEChERS adaptability for the analysis of pesticide residues in beehive products seeking the development of an agroecosystem sustainability monitor. Journal of Agricultural and Food Chemistry, 13 May 2015, Volume 63, Issue 18, Pages 4484-4492. Article history: Publication Date (Web): 16 Apr 2015Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : A - 1 |
Biblioteca(s): INIA La Estanzuela. |
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17. | | MIGUES, I.; RIVAS, F.; MOYNA, G.; KELLY, S. D.; HEINZEN, H. Predicting mandarin fruit acceptability: from high-field to benchtop NMR spectroscopy. Foods, 2022, volume 11, issue 16, article 2384. OPEN ACCESS. doi: https://doi.org/10.3390/foods11162384 Article history: Received 24 June 2022; Revised 29 July 2022; Accepted 1 August 2022; Published 9 August 2022.
Corresponding author: Heinzen, H.; Laboratorio de Farmacognosia y Productos Naturales, Departamento de Química Orgánica,...Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
Biblioteca(s): INIA Las Brujas. |
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18. | | REZENDE, S.; BANCHERO, S.; MIGUES, I.; CESIO, M.V.; RIVAS, F.; HEINZEN, H.; BESIL, M.N. Variability levels of selected amino acids among mandarins produced in Uruguay. Ecletica Quimica, 2021, Volume 46, Issue 4, Pages 47-59. Gold Open Access. doi: https://doi.org/10.26850/1678-4618eqj.v46.4.2021.p47-59 Article history: Received: July 27, 2020; Accepted: July 16, 2021; Published: October 01, 2021.
Section Editor: Assis Vicente Benedetti.
Corresponding author: María Natalia Besil. Email address: nbesil@fq.edu.uyTipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : Internacional - -- |
Biblioteca(s): INIA Las Brujas. |
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20. | | NIELL, S.; PAREJA, L.; ASTEGGIANTE, L.G.; ROEHRS, R.; PIZZUTTI, I.R.; GARCIA, C.; HEINZEN, H.; CESIO, M.V. Development of methods for multiresidue analysis of rice post-emergence herbicides in loam soil and their possible applications to soils of different composition. Journal of AOAC International, 2010, v. 93 no.2, p. 425-431. 2-s2.0-77952781014Tipo: Artículos en Revistas Indexadas Internacionales | Circulación / Nivel : B - 1 |
Biblioteca(s): INIA Las Brujas. |
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